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Article
Publication date: 1 September 2006

Maryam Ehteshamzadeh, Taghi Shahrabi and Mirghasem Hosseini

Aims to investigate the inhibitive effect of the new series of Schiff base molecules, namely, N, N′‐ethylen‐bis(salicylidenimine) [S1], N, N′‐isopropylen‐bis(salicylidenimine…

Abstract

Purpose

Aims to investigate the inhibitive effect of the new series of Schiff base molecules, namely, N, N′‐ethylen‐bis(salicylidenimine) [S1], N, N′‐isopropylen‐bis(salicylidenimine) [S2] and N, N′‐Ortho‐phenylen acetyl acetone imine, (2‐hydroxy Benzophenone imine) [S3] on corrosion of copper during acid pickling treatment in 1 M HCl solution. Effects of concentration and temperature on the inhibition efficiencies of the selected Schiff bases have been studied systematically.

Design/methodology/approach

All inhibition experiments were conducted on copper sample in 1 M HCl solution. Weight loss measurements were carried out according to the ASTM standard procedure. Polarization curves and impedance spectra were carried out in a three‐electrode cell assembly connected to an EG&G potentiostat M273 and frequency response analyzer M1025.

Findings

Results obtained revealed that the studied Schiff bases act predominantly as cathodic inhibitors. The variations in inhibition efficiencies mainly depend on the type and nature of the inhibitors. Polarization and ac impedance measurements carried out at different concentrations of studied Schiff bases revealed that these compounds are adsorbed on copper surface and the adsorption obeys Langmuir adsorption isotherm. From the adsorption isotherms, the values of equilibrium constant, Kads, and the free energies of adsorption, ΔGads, were calculated. The associated activation energy of corrosion and other thermodynamic parameters such as enthalpies and entropies have also been determined.

Practical implications

The presence of high efficiency and low cost inhibitors is essential in acid pickling treatments for protection of copper and lowering of acid consumption. In comparison with conventional copper corrosion inhibitors such as benzotriazole, this result would be considered as a step forward in determination of new corrosion inhibitor.

Originality/value

This paper reveals that Schiff bases can be successfully used for protection of copper surface in acid pickling solutions.

Details

Anti-Corrosion Methods and Materials, vol. 53 no. 5
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 1 May 2006

Maryam Ehteshamzadeh, Taghi Shahrabi and Mirghasem Hosseini

In this paper, the main aim is to study the synergistic effects of alkanethiols upon inhibition of Schiff bases, N,N′‐ethylen‐bis and N,N′‐ortho‐phenylen‐bis in 0.5 M sulphuric…

Abstract

Purpose

In this paper, the main aim is to study the synergistic effects of alkanethiols upon inhibition of Schiff bases, N,N′‐ethylen‐bis and N,N′‐ortho‐phenylen‐bis in 0.5 M sulphuric acid solutions.

Design/methodology/approach

Measurements were carried out in a three‐electrode cell assembly connected to the corrosion measurement system using software for Tafel polarization. Impedance measurements were carried out at open circuit potential using an electrochemical interface and frequency response analyzer at frequencies from 100 kHz to 10 MHz.

Findings

Results obtained revealed that at high concentrations, each of the investigated Schiff bases and 1‐dodecanethiol (DT) were good inhibitors when added separately to the corrosive media. The decrease in corrosion rate was associated with an increase in their concentrations. It was found that the presence of DT together with Schiff bases in corrosive medium increased inhibition effect, especially at low concentrations. Synergistic effect is discussed from viewpoint of their co‐adsorption. The adsorption of combined inhibitors was found to follow Langmuir isotherm. Thermodynamic calculations revealed that adsorption of combined inhibitors had a physical nature.

Research limitations/implications

In order to improve further the performance of Schiff bases and identifying their synergistic effects with other additives it is suggested that some more researches on other Schiff bases with other alkanethiol molecules must be done.

Practical implications

The results of this paper can be used for acid cleaning of carbon steel in which suitable inhibitor systems with the highest efficiency is required.

Originality/value

This paper reveals that the presence of DT molecules in solution encourage the adsorption of Schiff bases by facilitating the electrostatic co‐adsorption of Schiff base molecules through a synergistic effect.

Details

Anti-Corrosion Methods and Materials, vol. 53 no. 3
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 11 February 2021

Mahdi Jampour, Amin KarimiSardar and Hossein Rezaei Estakhroyeh

The purpose of this study is to design, program and implement an intelligent robot for shelf-reading. an essential task in library maintenance is shelf-reading, which refers to…

Abstract

Purpose

The purpose of this study is to design, program and implement an intelligent robot for shelf-reading. an essential task in library maintenance is shelf-reading, which refers to the process of checking the disciplines of books based on their call numbers to ensure that they are correctly shelved. Shelf-reading is a routine yet challenging task for librarians, as it involves controlling call numbers on the scale of thousands of books promptly.

Design/methodology/approach

Leveraging the strength of autonomous robots in handling repetitive tasks, this paper introduces a novel vision-based shelf-reader robot, called \emph{Pars} and demonstrate its effectiveness in accomplishing shelf-reading tasks. Also, this paper proposes a novel supervised approach to power the vision system of \emph{Pars}, allowing it to handle motion blur on images captured while it moves. An approach based on Faster R-CNN is also incorporated into the vision system, allowing the robot to efficiently detect the region of interest for retrieving a book’s information.

Findings

This paper evaluated the robot’s performance in a library with $120,000 books and discovered problems such as missing and misplaced books. Besides, this paper introduces a new challenging data set of blurred barcodes free publicly available for similar research studies.

Originality/value

The robot is equipped with six parallel cameras, which enable it to check books and decide moving paths. Through its vision-based system, it is also capable of routing and tracking paths between bookcases in a library and it can also turn around bends. Moreover, \emph{Pars} addresses the blurred barcodes, which may appear because of its motion.

Details

Industrial Robot: the international journal of robotics research and application, vol. 48 no. 5
Type: Research Article
ISSN: 0143-991X

Keywords

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